Skip to content

All-perovskite tandem solar cell based on tin-lead perovskite achieves 27.8% efficiency

  • by

Scientists in the United States have fabricated an all-perovskite tandem solar cell that reportedly shows reduced interfacial energy loss in the cell’s top device. It was built with a hole transport layer based on a compound known as P3CT that was doped with lead iodide.

JULY 11, 2024 EMILIANO BELLINI

Cross-sectional scanning electron microscope image of the cell

Image: University of Toledo

Share

A group of researchers led by the University of Toledo in the United States have fabricated an all-perovskite tandem solar cell with a wide-band-gap top cell based on tin-lead (Pb-Sn) perovskite and a low-band-gap bottom cell relying on a conventional perovskite substrate.

“The technology readiness level (TRL) of the tandem device investigated in this study is still low at TRLs 2-3,” the research’s corresponding author, Zhaoning Song, told pv magazine. “Our work, however, proves the feasibility of enhancing the stability of all-perovskite tandem solar cells, but more work needs to be done to apply this technique to industrial production.”

The key feature of the tandem cell is the top device’s hole transport layer (HTL), which was fabricated with a Pb-doped compound known as poly[3-(4-carbox- ybutyl)thiophene-2,5-diyl] (P3CT), a material that reportedly offers excellent stability and relatively high hole mobility.

“We introduce Pb doping to increase its work function and minimize the energy level offset with the Sn-Pb perovskite,” the academics explained, noting that P3CT represents a valid alternative to commonly used PEDOT-PSS. “The Pb dopants also provide nucleation sites to enable high-quality Sn-Pb perovskite film growth.”

The group built the top cell with a substrate made of indium tin oxide (ITO), the novel HTL, the Sn-Pb perovskite absorber, an electron transport layer (ETL) based on buckminsterfullerene (C60), a bathocuproine (BCP) buffer layer, and a silver (Ag) metal contact.

The champion cell built with this architecture achieved a power conversion efficiency of 22.7%, an open-circuit voltage of 0.884 V, a short-circuit current density of 32.0 mA cm2, and a fill factor of 80.3%. It was then combined in a tandem device with an 18.7%-efficient bottom cell based on a perovskite absorber with a bandgap of 1.7 eV, an HTL made of a phosphonic acid called methyl-substituted carbazole (Me-4PACz) and an ETL relying on C60.

The champion P3CT-based tandem achieved an efficiency of 27.8, an open-circuit voltage of 2.147 (2.146) V, a short-circuit current density of 15.7 mA/cm2, and a fill factor of 82.6%.

“The P3CT-based tandems also show a higher average efficiency of 27.0% than PEDOT: PSS-based devices, proving excellent reproducibility of the high-efficiency tandems with the P3CT-Pb HTL,” the group emphasized. “Doping P3CT with Pb cations reduced the valence band offset with Sn-Pb perovskite and provided nucleation seeds for enhancing perovskite crystallization, resulting in improved film quality.”

The P3CT-based tandem was also found to retain around 97% of its initial efficiency after 1,000 h.

According to Song, the cost of the doping technique is almost negligible, as the lead iodide material used for doping is the same source material used for producing the perovskite absorber layer, and only a trivial amount is needed for doping. “Yet, it is worth noting that the polymer hole-transport material used in this study is still expensive due to its complexity of synthesis and limited production scale,” he further explained.

The new cell technology was introduced in the study “Suppressed deprotonation enables a durable buried interface in tin-lead perovskite for all-perovskite tandem solar cells,” published in Joule. “Our molecular design strategy for stabilizing the perovskite/HTL interface provides a direction for achieving efficient and stable all-perovskite tandem solar cells,” the team concluded.

Leave a Reply

Your email address will not be published. Required fields are marked *

Thank You for contacting us. We will contact you soon……………

Thank You for contacting us. We will contact you soon……………